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MSDS: Veneer Bond Liquid Resin 1. Chemical Product & Company Identification DESCRIPTION: VENEER BOND LIQUID RESIN PRODUCT CODE: PG-L PRODUCT TYPE: MODIFIED UF LIQUID UF RESIN APPLICATION: GENERAL GLUING OF WOOD PRODUCTS MANUFACTURER/SUPPLIER INFORMATION San Juan Specialty Wood Products, Inc 1330 E. St. Andrew Pl, Ste “B” Santa Ana, CA 92705 For Product Information Call 1-888-342-8262 2. Composition Information On Ingredients The ingredients listed below have been associated with one or more immediate and/or delayed (*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDENT, READ AND UNDERSTAND THE MSDS. 50-00-0 * Formaldehyde by weight 1-2% 3. Hazards Identification 3.1 EMERGENCY OVERVIEW Appearance colorless/white opaque liquid Odor slight formaldehyde odor Hazardous polymerization may occur Not a significant fire hazard NO. AMERICAN EMERGENCY RESPONSE GUIDEBOOK, 1996, NO: 171 PRO-GLUE VENEER BOND LIQUID RESIN HMIS RATING HEALTH = 1 (slight) FLAMMABILITY = 0 (minimal) REACTIVITY = 0 (minimal) CHRONIC = * 3.2 POTENTIAL HEALTH EFFECTS IMMEDIATE HAZARDS INGESTION: no known hazards INHALATION: not expected to be harmful under normal conditions of use. however, if allowed to become airborne, may cause Irritation of nose, throat and lungs SKIN: may cause irritation on prolonged or repeated contact EYES: may cause irritation on prolonged or repeated use DELAYED HAZARDS FORMALDEHYDE 50-00-0 POTENTIAL CANCER HAZARD Rats chronically exposed to 14 ppm formaldehyde contracted nasal cancers. Based on animal data and limited epidemiological evidence, NTP and IARC have listed formaldehyde as a probable human carcinogen. OSHA regulates formaldehyde as a potential human carcinogen. May cause allergic skin reaction. Some reports suggest that formaldehyde may cause respiratory sensitization such as asthma and that pre-existing respiratory and skin disorders may be aggravated by exposure. OSHA has identified 0.5 ppm as the “action level”, 29CRF 1910.1048. please refer to the OSHA Standard for guidance applicable to your specific operation. 4. First Aid Measures INGESTION: if accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for other treatment directions. INHALATION: remove to fresh air Read next page PRO-GLUE VENEER BOND LIQUID RESIN SKIN: in case of irritation, flush with water Eyes: immediately flush with plenty of water. Call a physician if irritation persists. 5. Fire Fighting Measures Flash point: not applicable Lower explosion: not applicable Upper explosion limit: not applicable Auto ignition temperature: not applicable 6. Accidental Release Measures Large quantities: enclose with diking material to prevent seepage into natural bodies of water, then consult SAN JUAN SPECIALTY WOOD PRODUCTS, INC. Small quantities: soak up with absorbent material and remove to a chemical disposal area. 7. Handling And Storage 7.1 HANDLING Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from the eyes, skin and clothing. Wash thoroughly after handling. SKIN: avoid prolonged or repeated contact with skin and clothing EYES: avoid prolonged or repeated contact with the eyes 7.2 STORAGE Not harmed by freezing, but thaw frozen resin slowly and stir before using. Store in a cool place; high temperatures shorten storage life. Urea formaldehyde resin thickens with age. Rotate stock in storage use oldest product first. Limited storage life-refer to product specifications. Solubility in water of urea resins can vary from infinite to insoluble depending on manufacturing procedure and age. Warm water helps in washing up resins with limited solubility. 8. Exposure Controls/Personal Protection 8.1 EXPOSURE CONTROLS If airborne contaminates are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contamination levels below acceptable criteria 8.2 PERSONAL PROTECTION Where air contaminates can exceed acceptable criteria, use NIOSH/MSHA approved full face piece respiratory equipment. Respirators should be selected based on the form and concentration of contaminates in the air in accordance with OSHA 29CFR 1910.1048(g). RESPIRATORY PROTECTION, OSHA 29CFR 1910.134 or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Wear chemical splash goggles or some other type of complete protection for the eye if contact is likely. Wear protective (impervious) gloves as required to prevent skin contact. Where high concentrations of hazardous ingredients may be present, such as in an emergency, full body protection should be worn. Other protective equipment: eye wash fountain, safety shower, reusable protective clothing should be cleaned and ventilated after any formaldehyde contamination. See OSHA 29CFR 1910.1048(h) protective equipment and clothing and OSHA 29CFR 19010.1048(i) hygiene protection for other specific requirements based on the form of formaldehyde, the conditions of use and the hazards to be prevented. 8.3 EXPOSURE GUIDELINES Formaldehyde 50-00-0 ACGIH TLV: 0.3 ppm (0.37 mg/m3) ceiling, A2 – See appendix A OSHA PEL: 0.75 ppm(0.0 mg/m3); 2 ppm (2,5mg/m3) 15min STEL 9. Physical And Chemical Properties Appearance colorless/white opaque liquid Odor: slight formaldehyde odor Odor: threshold: n/a Specific gravity ~1.29 pH !7.6 @ 26C Viscosity, Brookfield n/a Freezing point -10C Solubility in water see storage section Octanol/ water partition coefficient n/a Vapor pressure @ 25c ~22 MG Hg Vapor density (air=1) n/a Evaporation point (butyl acetate=1) ~0.3 Boiling point, 760 mm Hg ~102C Typical % solids ~65.00% 10. Stability And Reactivity Normally stable as defined in NFPA 704-12-(4-3.1) DECOMPOSITION PRODUCTS MAY INCLUDE: CO, CO2, aldehydes (including formaldehyde), hydrogen cyanide, particulate matter and other organic compounds by thermal decomposition in air. HAZARDOUS POLYMERIZATION: May occur 11. Toxicological Information Ingestion: a similar product was found to be non-toxic orally when tested as described in 16 CFR part 1500.3(c) (1) and (2). Inhalation: a similar product was found to be non-toxic by inhalation when tested as described in 16 CFR part 1500.3 (c) (1) and (2). Skin a similar product was found to be non-toxic dermally when Absorption: as described in 16 CFR part 1500.3 (c) (1) and (2) Skin: a similar product was not a primary irritant(primary skin irritation index less than 5.0/8.0) when tested as described in 16 CFR part 1500.41 Eyes: a similar product was slightly irritating when tested as described in CFR 16 part 1500.42 Formaldehyde: 50-00-0 LC50: rat = 203 mg/m3 (RTECS) LD50: orl-rat = 0.8 g/kg (Merck); skn – rbt = 0.27 g/kg (Sax) 12. Ecological Information No data for ecotoxicity has been found. Effects are expected to be minimal The material is a soil mobile liquid initially which will solidify on aging. Biodegradation is expected to be very slow: bioaccumulation negligible. 13. Disposal Considerations Recover free liquid. Absorb residue and dispose of according to local, state/provincial and federal requirements. 14. Transport Information 14.1 U.S DEPARTMENT OF TRANSPORTATION (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Environmentally hazardous substances, liquid, nos., (formaldehyde), 9, UN3082, III, NA ERG (1996): 171 14.2 CANADIAN TRANSPORATION OF DANGEROUS GOODS (TDG) Bulk shipments regulated as: Environmentally hazardous substances, liquid, N.O.S. (formaldehyde) Class 9.2 UN3082 Pk. Gr III Tote tanks and smaller containers non-regulated 15. Regulatory Information (SELECTED REGULATIONS) 15.1 U.S. FEDERAL REGULATIONS OSHA HAZARD COMMUNICATION STANDARD 29CFR1910.1200 This material presents a possible health hazard as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 “hazard communication” standard. SARA TITLE III: SECTION 311/312 Reactivity hazard Delayed health hazard --------------------------------------------------------------------------------------------------- SARA TITLE III SECTION 313 AND 40 CFR PART 372 This product contains the following toxic chemical (s) subject to the reporting requirements of section 313 of title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR part 372 Formaldehyde 50-00-0 2.5% TSCA SECTION 8(b) INVENTORY All reportable substances are listed on the TSCA inventory. We rely on certification of compliance from our suppliers for chemical substances not manufactured by SAN JUAN SPECIALITY WOOD PRODUCTS, INC. 15.2 CANADIAN REGULATIONS WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Class D, Div 2A CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. NATIONAL POLLUTANT RELEASE INVENTORY (NPRI) This product contains the following chemical (s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16 (1), National Pollutant Release Inventory. Formaldehyde 50-00-0 2.5% 16. Other Information User’s Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with the use of this product and its ingredients. DISCLAIMER SELLER MAKES NO WARRANTY, EXPRESS OR OTHERWISE IMPLIE, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications and that the product does not infringe any valid UNITED STATES or CANADIAN patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall seller be liable for incidental or consequential damages, whether buyer’s claim is based on contract, breach of warranty, negligence or otherwise. |
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