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MSDS: Veneer Bond Hardener Light and Dark Light Hardener 1. Chemical Product and Company Identification DESCRIPTION: CASCOSET FM-203A PRODUCT CODE: 36-203AH-. PRODUCT TYPE: DRY CATALYST APPLICATION: HIGH FREQUENCY UF RESIN CURE Manufacturer/Supplier Information Read and understand this before using or handling product. For emergency purposes: PRO-GLUE, a product line of VAC-U-CLAMP PRO-GLUE Emergency phone: 888-342-8262 CHEMICAL HAZARD RATING Health=2 (moderate) Fire=2 (moderate) Reactivity=0 (least) 2. Composition, Information on Ingredients The ingredients listed below have been associated with one or more immediate and/or delayed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING OR HANDLING, READ AND UNDERSTAND THE MSDS. % by weight 12125-02-9 Ammonium Chloride - 3. Hazards Identification 3.1 Emergency Overview Appearance Dry powder Odor Little or none Combustible dust when finely divided or suspended in air. May be harmful if inhaled. Eye irritant. DESCRIPTION: CASCOSET FM-203A PAGE 2 OF 6 3.2 Potential Health Effects Immediate Hazards INGESTION: Not expected to be harmful under normal conditions of use. INHALATION: May be harmful if inhaled. Dust or vapor may cause irritation of nose, throat and lungs. SKIN: May cause irritation on prolonged or repeated contact. EYES: Causes irritation. Delayed Hazards None of the components present in this product at concentrations equal to or greater than 0.1% have been listed by NTP, classified by IARC, nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidently swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Call a physician. SKIN: In case of irritation, flush with water. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with entire surface of eyes and lids. Call a physician. 5. Fire Fighting Measures Flash point Not applicable Lower explosion limit Not applicable Upper explosion limit Not applicable Autoignition temperature Not applicable Will burn. Refer to NFPA Pamphlet No. 654, “Prevention of Fire and Dust Explosions in the Chemical, Dye, Pharmaceutical, and Plastic Industries, if this material is to be reduced to or collected as a powder. In case of fire, water should be used to keep fire-exposed containers cool. 6. Accidental Release Measures Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash thoroughly after handling. INHALATION: Avoid breathing dust or vapor. Use with adequate ventilation. SKIN: Avoid prolonged or repeated contact with skin and clothing. EYES: Avoid contact with eyes. 7.2 Storage Store in a cool, dry place. If exposure to moisture causes lumping, break lumps into powder before using. Storage life at 70 F is one year, less at higher temperatures. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices. These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recormtiend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria. 8.2 Personal Protection Where air contaminants can exceed acceptable criteria, use NIOSH/MSHA approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA 29 CFR 1910.134 or other applicable standards or guidelines. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact. 8.3 Exposure Guidelines nunonium Chloride 12125-02-9 ACGIH TLV: Fume 10 mg/rn3 TWA; 20 mg/rn3 STEL OSHA PEL: NONE ESTABLISHED REMANDED PEL: Fume 10 mg/rn3 TWA; 20 mg/rn3 STEL OSHA 1989 PEL remanded, but in effect in some states 9. Physical and Chemical Properties Appearance Dry powder Color Off white/Beige Odor Little or none 10. Stability and Reactivity Normally stable as defined in NFPA 704-12(4-3.1). In common with most organic materials, this product should be treated as a combustible dust in the finely divided and suspended state. Incompatibilities: Oxidizers such as potassium chlorate and potassium nitrate. Hazardous polymerization: Will not occur. 11. Toxicological Information Ainmoniunt Chloride 12125-02-9 LC5O: Not available LD5O: orl-rat=l650 mg/kg (Sax) 12. Ecological Information Not determined. 13. Disposal Considerations Dispose of according to local, state/provincial, and federal requirements. 14. Transportation 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Not Regulated 14.2 Canadian Transportation of Dangerous Goods (TDG) Not determined. 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations OSIIA Hazard Communication Standard 29CFR1910.1200 This material is a health hazard and/or a “physical hazard” as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 “Hazard Communication” Standard. SARA Title III: Section 311/312 Immediate health hazard SARA Title III Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C-Supplier Notification Requirement of 40 CFR Part 372. None required per SARa TITLE III SECTION 313. TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by PRO-GLUE. 15.2 Canadian Regulations DESCRIPTION: CASCOSET FM-203A PAGE 6 OF 6 Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. CLASS D, DIV 2B Canadian Enviromnental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other Information Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer’s claim is based on contract, breach of warranty, negligence or otherwise. CUR ISSUE 08-OCT-96 PREVIOUS ISSUE: 13-SEP-96 PRINT DATE: June 6, 1997 01:36 PM 040 36-203AH-. THIS IS THE LAST PAGE User’s Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Instruct your workers to handle this product properly. Dark Hardener 1. Chemical Product and Company Identification DESCRIPTION: Cascoset® FM-203W PRODUCT CODE: 36-203WH-. PRODUCT TYPE: Dry Catalyst APPLICATION: Cold Press/High Frequency UF Resin Cure Manufacturer/Supplier Information MSDS prepared by: PRO-GLUE Emergency phone: 888-342-8262 Product Type: Relaxing Agent General product use: Veneer Plasticizer 2. Composition, Information on Ingredients The ingredients listed below have been associated with one or more immediate andlor delayed(*) health hazards. Risk of damage and effects depends upon duration and level of exposure. BEFORE USING, HANDLING, OR EXPOSURE TO THESE INGREDIENTS, READ AND UNDERSTAND THE MSDS. % by weight 7778-18-9 Calcium Sulfate (CaSO4) 10.0 - 30.0 9004-34-6 Cellulose 10.0 - 30.0 1332-58-7 *Kaoljn 10.0 - 30.0 12125-02-9 Ammonium Chloride 5.0 - 10.0 7783-20-2 Ammonium Sulfate 5.0 - 10.0 3. Hazards Identification 3.1 Emergency Overview Appearance White powder Odor Slight ammonia CAUTION! Combustible dust when finely divided or suspended in air. May be harmful if inhaled. May cause irritation of nose, throat and lungs. Causes eye irritation. HMIS Rating HEALTH FLAMMABILITY = 2 (moderate) REACTIVITY = 1 (slight) CHRONIC = * 0 (minimal) 3.2 Potential Health Effects Delayed Hazards 1332-58-7 Kaolin Chronic inhalation has resulted in benign pneumoconiosis. Pre-existing respiratory disorders may be aggravated by exposure. -- See Footnote Footnote: As of the date of issuance of this document, this material has not been listed by NTP, classified by IARC nor regulated by OSHA as a carcinogen. 4. First Aid Measures INGESTION: If accidentally swallowed, dilute by drinking large quantities of water. Immediately contact poison control center or hospital emergency room for any other additional treatment directions. INHALATION: If inhaled, remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Call a physician. SKIN: In case of irritation, flush with water. EYES: Immediately flush eyes with plenty of water for at least 15 minutes. Eyelids should be held apart during irrigation to insure water contact with entire surface of eyes and lids. Call a physician. Immediate Hazards INGESTION: Not expected to be harmful under normal conditions of use. INHALATION: May be harmful if inhaled. Dust or vapor may cause irritation of nose, throat and lungs. SKIN: May cause irritation on prolonged or repeated contact. EYES: Causes irritation. 5. Fire Fighting Measures Flash point Not applicable Lower explosion limit Not applicable Upper explosion limit Not applicable Autoignition temperature Not applicable Will burn. Refer to NFPA Pamphlet No. 654, “Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids,” if this material is to be reduced to or collected as a powder. In case of fire, use water spray, dry chemical, “alcohol” foam or C02. Use water to keep fire-exposed containers cool. 6. Accidental Release Measures Sweep (scoop) up and remove to a chemical disposal area. Prevent entry into natural bodies of water. 7. Handling and Storage 7.1 Handling Handle in accordance with good industrial hygiene and safety practices. These practices include avoiding unnecessary exposure and removal of the material from eyes, skin and clothing. Wash thoroughly after handling. Always use appropriate Personal Protective Equipment (PPE). INHALATION: Avoid breathing dust or vapor. Use with adequate ventilation. SKIN: Avoid prolonged or repeated contact with skin and clothing. EYES: Avoid contact with eyes. 7.2 Storage Store in a cool, dry place. If exposure to moisture causes lumping, break lumps into powder before using. Storage life at 700 F is one year, less at higher temperatures. 8. Exposure Controls/Personal Protection 8.1 Exposure Controls ENGINEERING CONTROLS: The following exposure control techniques may be used to effectively minimize employee exposure: local exhaust ventilation, enclosed system design, process isolation and remote control in combination with appropriate use of personal protective equipment and prudent work practices. These techniques may not necessarily address all issues pertaining to your operations. We, therefore, recommend that you consult with experts of your choice to determine whether or not your programs are adequate. If airborne contaminants are generated when the material is heated or handled, sufficient ventilation in volume and air flow patterns should be provided to keep air contaminant concentration levels below acceptable criteria. 8.2 Personal Protection Where air contaminants can exceed acceptable criteria, use NIOSH (42 CFR Part 84) approved respiratory protection equipment. Respirators should be selected based on the form and concentration of contaminants in air in accordance with OSHA laws and regulations or other applicable standards or guidelines, including ANSI standards regarding respiratory protection. Use goggles if contact is likely. Wear impervious gloves as required to prevent skin contact. 8.3 Exposure Guidelines 9. Physical and Chemical Properties Appearance White powder Odor Slight ammonia Odor threshold Not available Specific gravity Not available pH Not available Viscosity Not available Freezing point Not available Solubility in water Not available Octanollwater partition coefficient Not available Vapor pressure Not available Vapor density Not available Evaporation rate Not available Boiling point, 760 mm Hg Not available ACGIH TLV OSHA PEL 7778-18-9 8-hr TWA 10 mg/m3 Particles (Insoluble or Poorly Soluble) Not Otherwise Specified 8-hr TWA 5 mg/m3 respirable 8-hr TWA 15 mg/m3 total dust Calcium Sulfate (CaSO4) ACGIH TLV OSHA PEL 9004-34-6 8-hr TWA 10 mg/m3 inhalable particulate 8-hr TWA 5 mglm3 respirable particulate 8-hr TWA 15 mglm3 total dust Cellulose ACGIH TLV OSHA PEL 1332-58-7 8-hr TWA 10 mg!m3 8-hr TWA 5 mglm3 respirable particulate 8-hr TWA 15 mg/m3 total dust Kaolin ACGIH TLV OSHA PEL 12125-02-9 8-hr TWA 2 mg/m3 respirable fraction 8-hr TWA 5 mg/m3 respirable fraction 8-hr TWA 15 mg/m3 total dust Remanded TWA 5 mglm3 respirable fraction Remanded TWA 10 mglm3 total dust; 1989 PEL remanded, but in effect in some states Ammonium Chloride ACGIH TLV OSHA PEL 7783-20-2 8-hr TWA 10 mg/m3 Fume STEL (15 mm) 20 mg/m3 None Established Remanded TWA 10 mg!m3 Fume; 1989 PEL remanded, but in effect in some states Remanded STEL 20 mg/m3 Ammonium Sulfate 10. Stability and Reactivity Nonnally stable as defined in NFPA 704-12(4-3.1). In common with most organic materials, this product should be treated as a combustible dust in the finely divided and suspended state. Incompatibilities: Oxidizers such as potassium chlorate and potassium nitrate. Hazardous polymerization: Will not occur. 11. Toxicological Information See Section 3 Hazards Identification information. 7778-18-9 Calcium Sulfate (CaSO4) LC5O: Not available LD5O: Not available 9004-34-6 Cellulose LC5O: Not available LD5O: Not available 1332-58-7 Kaolin LC5O: Not available LD5O: Not available 12125-02-9 LC5O: Not available LD5O: Oral-rat= 1,650 mg/kg (Sax) 7783-20-2 Ammonium Sulfate LC5O: Not available LD5O: Not available Ammonium Chloride 12. Ecological Information Not determined 13. Disposal Considerations Dispose of according to local, state/provincial, and federal requirements. 14. Transport Information 14.1 U.S. Department of Transportation (DOT) The data provided in this section is for information only and may not be specific to your package size. You will need to apply the appropriate regulations to properly classify your shipment for transportation. Regulation: Non regulated 14.2 Canadian Transportation of Dangerous Goods (TDG) Regulation: Non regulated 15. Regulatory Information (Selected Regulations) 15.1 U.S. Federal Regulations OSHA Hazards Communication Standard 29CFR1910.1200 This material is a “health hazard” and/or a “physical hazard” as determined when reviewed according to the requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 “Hazard Communication” Standard. SARA Title III: Section 311/312 Immediate health hazard Delayed health hazard SARA Title III: Section 313 and 40 CFR Part 372 This product contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986, and Subpart C- Supplier Notification Requirement of 40 CFR Part 372. None required per SARA TITLE III SECTION 313. TSCA Section 8(b) Inventory All reportable chemical substances are listed on the TSCA Inventory. We rely on certifications of compliance from our suppliers for chemical substances not manufactured by us. 15.2 Canadian Regulations Workplace Hazardous Materials Information System (WHMIS) This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR) and the MSDS contains all the information required by the CPR. Class D2B Canadian Environmental Protection Act (CEPA) All reportable chemical substances are listed on the Domestic Substances List (DSL) or otherwise comply with CEPA new substance notification requirements. National Pollutant Release Inventory (NPRI) This product contains the following chemical(s) subject to the reporting requirements of the Canadian Environmental Protection Act (CEPA) subsection 16(1), National Pollutant Release Inventory. None required. 16. Other information User’s Responsibility The OSHA Hazard Communication Standard 29CFR 1910.1200 and the Workplace Hazardous Materials Information System (WHMIS) require that the information contained on these sheets be made available to your workers. Educate and train your workers regarding OSHA and WHMIS precautions. Instruct your workers to handle this product properly. Consult with appropriate experts to guard against hazards associated with use of this product and its ingredients. Disclaimer SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential damages, whether Buyer’s claim is based on contract, breach of warranty, negligence or otherwise. |
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